Here you have a picture of the instructions, what, where and how to connect to the boiler:
According to the description:
"the bridge between terminals 3 and 4 is not removed if a temperature control system is connected or a room temperature control system (continuous control - terminals 7, 8, 9)" - some of the Vaillant controllers were connected with a 3-wire cable for terminals 7-8-9, and newer with a 2-wire cable for terminals +/- E-Bus, both are communication buses with devices and these cables cannot be shorted.
In your case, if you unplug the Vaillant "colormate 360" regulator, you will be able to connect any thermostat / regulator that works on / off, but under terminals 3-4, where the jumper is!
Only, as I wrote, it must be a potential-free contact, i.e. on / off = closed / open. Potential-free is one that does not give any voltage.