Hi,
markings suggest me that they are shottkey diode, if they are really zener diode how they are connected looks a bit interesting.
Pin 7 is a power supply here zener diode make sens, but scheme looks strange, ZD3 should be to base and resistro is between base nad collector. This diode should be <36V while this is the limit for the microchip.
ZD1 make no sens, if this is zener diode it limit/reduce the potential on FB pin, but it not make sens while pin 1 is on GND. Shottkey diode seems more logical but are you sure about connection? My guess is to protect the transistor in optocoupler.
D4 seems to be switching/fast diode.
Regards