You make interesting combinations with the boiler, but there are a few problems.
1) Even a 100-120 liter boiler will not store too much energy. Quite simply, there is not enough water in the tank. Buffers are usually from 300l for a floor heating (working at low temperature and a buffer at high temperature) to 1000l (and even more for radiators).
2) The 2500W heater is not only a little bit to not only slowly heat the buffer, but also to heat the apartment on an ongoing basis. Assuming that the energy is taken from the buffer around the clock and it is at a rate of 2kWh around 0 degrees outside, it is difficult to build up the energy reserve in the buffer for the daily tariff and to heat the apartment when the demand increases due to frosts.
c) the horizontal boiler is a weak buffer because the water in it mixes quickly.
It follows that, especially for radiators, electric heating from a buffer with accumulation (because only this makes sense when using a buffer) must:
a) have the heaters' heating capacity installed, preferably at least 2 times greater than the maximum hourly demand of the premises. So if, while heating, you have used, for example, 60kWh / day, which gives an average power of 2.5kW, the heaters must be at least 5kW
b) the tank must store enough energy so that the heaters do not need to be turned on in the daily tariff. So either a higher capacity or / and a higher storage temperature of water in the buffer (for radiators operating on 50 degrees of supply this is unfavorable than for the floor heating)
c) you need a mixing installation at the outlet from the buffer, so that when you collect, for example, 300l of water at a temperature of 80 degrees, do not let it go on the radiators, but go on CO, e.g. 50 degrees
d) to use the full energy of the buffer, so that in the half of the working time during the day, while drawing energy from the buffer, there is suddenly no lack of heat from it, the tank (buffer) should be in a vertical arrangement to take advantage of the thermal stratification of the water