You have to check in the bios before windows will start. When windows starts to start, there is no need to check it anymore.
BTW recently I had the same symptom in several FSCs - a weak battery.
What did the colleague measure the battery with?
Maybe a colleague will replace it prophylactically? CR2032 should be max 3V and not 3.38.
Besides, I haven't read anywhere what kind of motherboard it is.
And last but not least - does the colleague of the Author have any illegal, non-original or cracked program on the computer? ?